Genesis 19:24
King James Version
24 Then the Lord rained upon Sodom and upon Gomorrah brimstone and fire from the Lord out of heaven;
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Deuteronomy 29:23
King James Version
23 And that the whole land thereof is brimstone, and salt, and burning, that it is not sown, nor beareth, nor any grass groweth therein, like the overthrow of Sodom, and Gomorrah, Admah, and Zeboim, which the Lord overthrew in his anger, and in his wrath:
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Psalm 11:6
King James Version
6 Upon the wicked he shall rain snares, fire and brimstone, and an horrible tempest: this shall be the portion of their cup.
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Isaiah 30:33
King James Version
33 For Tophet is ordained of old; yea, for the king it is prepared; he hath made it deep and large: the pile thereof is fire and much wood; the breath of the Lord, like a stream of brimstone, doth kindle it.
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Ezekiel 38:22
King James Version
22 And I will plead against him with pestilence and with blood; and I will rain upon him, and upon his bands, and upon the many people that are with him, an overflowing rain, and great hailstones, fire, and brimstone.
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