Deuteronomy 19:4-6
New Revised Standard Version, Anglicised Catholic Edition
4 Now this is the case of a homicide who might flee there and live, that is, someone who has killed another person unintentionally when the two had not been at enmity before: 5 Suppose someone goes into the forest with another to cut wood, and when one of them swings the axe to cut down a tree, the head slips from the handle and strikes the other person who then dies; the killer may flee to one of these cities and live. 6 But if the distance is too great, the avenger of blood in hot anger might pursue and overtake and put the killer to death, although a death sentence was not deserved, since the two had not been at enmity before.
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